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5 5 5 5 5 I I I 8 4 I 4 Q g g g g B B B ) + + + + + + $ " V O 5 B B O 5 5 g g d R 5 g 5 g ) ) g ? I R z 0 " / " " 5 h B v T D P ; B B B O O B B B " B B B B B B B B B : CHMD59F/CHM1425H/EES1121H
Modeling the Fate of Organic Chemicals in the Environment
This course will give an introduction to quantitative approaches to describing the behaviour of organic chemicals in the environment. Building upon a quantitative treatment of equilibrium partitioning and kinetically controlled transfer processes of organic compounds between gaseous, liquid and solid phases of environ mental significance, it will be shown how to build, use, and evaluate simulation models of organic chemical fate in the environment. The course will provide hands on experience with a variety of such models.
Instructor: F. Wania
Office SY-364 (ϲʿӿ)
Tel. 416-287-7225
E-mail: HYPERLINK mailto:frank.wania@utoronto.ca frank.wania@utoronto.ca
Format: 2 hours lecture, followed by 1 hour tutorials
Time: Wednesday, 9:00 to 12:00
Location: BV 264, UTSC Campus
Office Hours: Wednesday, 13:00-15:00, or by appointment
Grading: CHM1425H CHMD59F
EES1121H
2 Take-home assignments 20 % 30 %
Paper summaries 10 % 10 %
1 Term project/paper 30 % 30 %
1 Project presentation 10 %
1 Final Exam 30 % 30 %
For those taking the course at the graduate level:
- the expectation with respect to the term project/paper are higher
- a short oral presentation on the term paper/project is expected
- the final exam will include more challenging questions
Prerequisites: An introductory course in each of organic, physical and environmental chemistry.
Textbook: Not any one text book includes all of the material covered in this course. Reading assignments (e.g. textbook chapters, scientific publications) will be given during each lecture. Useful for reference will be the following books:
Mackay, D. Multimedia Environmental Models. The Fugacity Approach. Lewis Publ. Chelsea, MI
Schwarzenbach, R., Gschwend, P., Imboden. Environmental Organic Chemistry. J. Wiley & Sons, NY
These books will be available in SY-364.
Course Outline
#DateTopic (tentative)1Sept. 14Introduction: Motivation and Mass Balance
System Definition2Sept. 21Segmentation/Compartmentalisation
(given by Dr. Jon Arnot)3Sept. 28Expressing Equilibrium Phase Distribution: Distribution Coefficients and Linear Free Energy Relationships4Oct. 5Expressing Equilibrium Phase Distribution: Measurement, Estimation and Selection of Phase Partitioning Equilibria5Oct. 11Expressing Equilibrium Phase Distribution: Equilibrium Models and the Chemical Partitioning Space
(given by Dr. Jon Arnot)6Oct. 19Expressing Kinetic Phenomena: Transformation and Advective Transport7Oct. 26Expressing Kinetic Phenomena: Diffusive Transport Processes8Nov. 2Application of Simple Steady-State Models: Assessment of Persistence and Long Range Transport Potential, Sensitivity and Uncertainty Analysis9Nov. 9Application of Non-Steady-State Models: Understanding Time Trends10Nov. 16Modelling Bioaccumulation and Food Chain Transfer of Contaminants11Nov. 23Modelling Global Contaminant Fate and Transport12Nov. 30Student presentations on term project by those taking the course at the graduate levelDec. 7Due date for term projects/papers
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